Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting     

Kosei Komuro    Katsuyuki Yamaguchi  Yoshimichi Kajiwara 《Resource Geology》2005,55(4):337-351

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.  相似文献   

Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography     

Kosei Komuro  Koji Wakita 《Resource Geology》2005,55(4):321-336

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.  相似文献   

Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan   总被引：1，自引：0，他引：1  

Yasuhiro Kato    Koichiro Fujinaga  Tatsuo Nozaki    Kentaro Nakamura    Ryuji Ono  Hiroshi Osawa 《Resource Geology》2005,55(4):291-300

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.  相似文献   

Age and significance of core complex formation in a very curved orogen: Evidence from fission track studies in the South Carpathians (Romania)   总被引：1，自引：1，他引：1  

B. Fügenschuh  S.M. Schmid 《Tectonophysics》2005,404(1-2):33-53

Twenty-four new zircon and apatite fission track ages from the Getic and Danubian nappes in the South Carpathians are discussed in the light of a compilation of published fission track data. A total of 101 fission track ages indicates that the Getic nappes are generally characterized by Cretaceous zircon and apatite fission track ages, indicating cooling to near-surface temperatures of these units immediately following Late Cretaceous orogeny.The age distribution of the Danubian nappes, presently outcropping in the Danubian window below the Getic nappes, depends on the position with respect to the Cerna-Jiu fault. Eocene and Oligocene zircon and apatite central ages from the part of the Danubian core complex situated southeast of this fault monitor mid-Tertiary tectonic exhumation in the footwall of the Getic detachment, while zircon fission track data from northwest of this fault indicate that slow cooling started during the Latest Cretaceous. The change from extension (Getic detachment) to strike-slip dominated tectonics along the curved Cerna-Jiu fault allowed for further exhumation on the concave side of this strike-slip fault, while exhumation ceased on the convex side. The available fission track data consistently indicate that the change to fast cooling associated with tectonic denudation by core complex formation did not occur before Late Eocene times, i.e. long after the cessation of Late Cretaceous thrusting.Core complex formation in the Danubian window is related to a larger-scale scenario that is characterized by the NNW-directed translation, followed by a 90° clockwise rotation of the Tisza-Dacia “block” due to roll-back of the Carpathian embayment. This led to a complex pattern of strain partitioning within the Tisza-Dacia “block” adjacent to the western tip of the rigid Moesian platform. Our results suggest that the invasion of these southernmost parts of Tisza-Dacia started before the Late Eocene, i.e. significantly before the onset of Miocene-age rollback and associated extension in the Pannonian basin.  相似文献   

Prolonged postcollisional shoshonitic magmatism in the southern Svecofennian domain – a case study of the Åva granite–lamprophyre ring complex     

Olav Eklund  Alexey Shebanov 《Lithos》2005,80(1-4):229-247

The Åva ring complex is one of four Paleoproterozoic postcollisional shoshonitic ring complexes in southwestern Finland. It is composed of ring dykes of K-feldspar megacryst-bearing granite, mingled in places with a shoshonitic monzonite, and lamprophyre dykes crosscutting all the rocks in a radial pattern. A survey was undertaken to trace the magma chamber beneath the ring complex to date it and measure some intensive parameters to clarify the crystallisation conditions at depth before the granite was emplaced in the upper crust. Mineral separates were extracted from the core zones of K-feldspar megacrysts in the granite, heavy mineral fractions (including zircons) from these separates were used for P-T assessment and age determinations, and the results were compared to data obtained from bulk rock samples. It appears that magma differentiation took place in a midcrustal magma chamber (at 4 to 7 kbar) possibly 30 Ma before the emplacement of the ring complex in the upper crust (deep assemblage 1790 Ma, shallow assemblage 1760 Ma). Relatively high activity of the alkalies and a low oxygen fugacity characterised the midcrustal chamber. The juvenile Svecofennian crust was invaded by shoshonitic magmas from an enriched lithospheric mantle over a long period of time. Some of these magmas were stored and differentiated in the middle crust before transportation to the upper crust. The results also show that coarse-grained granites may provide evidence for several magmatic evolutionary episodes, e.g., differentiation and crystallisation in different environments prior to final emplacement.  相似文献   

扬子陆块~2.0 Ga的区域变质事件对南北黄陵古元古代差异演化的启示     

陈超  苑金玲  郭盼  黎方云  孔令耀  杨金香  毛新武 《中国地质》2020,47(4):899-913

扬子陆核黄陵地区发育较为完整的太古宙—古元古代片麻岩、表壳岩组合(即崆岭杂岩),前人调查研究认为南北黄陵Ar-Pt1具有一致的物质组成和地质演化过程。笔者分别对南北黄陵太古宙花岗质片麻岩进行锆石年代学研究发现,北黄陵2件样品(HL013-1、HL013-2)均存在大量锆石发育岩浆核-变质边结构,都获得～2.8 Ga原岩结晶年龄和～2.0 Ga变质年龄;而南黄陵1件样品(HL005-3)以具振荡环带结构的岩浆锆石为主,仅获得～2.9 Ga原岩结晶年龄。结合前人研究成果发现,～2.0 Ga的变质年龄在北黄陵太古宙—古元古代的花岗片麻岩、表壳岩中广泛发育,而在南黄陵相似建造中均未获得,一定程度上说明北黄陵地区广泛遭受～2.0 Ga的区域变质作用而南黄陵不发育,南北黄陵在古元古代可能处在不同地块或者同一地块不同部位。2.1～1.6 Ga的构造岩浆事件的分布特点说明扬子陆块可能存在多条古元古代造山带,扬子陆块古元古代以多块体拼贴为特点,广泛记录2.1～1.6 Ga的构造岩浆事件说明扬子陆块是全球哥伦比亚超大陆的重要组成部分。  相似文献   

秦岭造山带多金属矿普查复杂地层护壁堵漏技术          下载免费PDF全文

柳硕林  韩明耀 《探矿工程》2020,47(1):43-47

秦岭造山带多金属矿普查项目钻探施工过程中钻遇多种复杂地层，垮塌、缩径、漏失等复杂情况频发，严重影响了施工效率。分别采用了植物胶钙处理钻井液、聚乙烯醇无固相钻井液等进行护壁工作，结合不同漏失情况分别实施了随钻堵漏、凝胶堵漏等技术措施，取得了良好的使用效果。  相似文献   

复杂卫星图像中的小目标船舶识别   总被引：1，自引：1，他引：0  

姚红革  王诚  喻钧  白小军  李蔚 《遥感学报》2020,24(2):116-125

船舶作为海上的重要目标,实现对船舶自动识别有重要的意义。针对卫星图像中云雾、海岸背景等复杂海情对船舶识别带来的干扰,以及小目标船舶高漏检率问题,本文提出一种多尺度深度学习模型训练策略,在此基础上构建了一种船舶识别的深度学习网络,该网络可分为多尺度训练、特征提取、生成目标建议区域、船舶分类这4个部分。首先,采用多尺度的训练策略,将多尺度的船舶样本送入网络中进行训练,这样在训练样本中加入了大量小目标船舶的样本,使网络充分提取到小目标船舶的特征;其次,通过卷积神经网络对目标船舶进行特征自适应提取;然后,目标区域建议网络可依据卷积神经网络提取到的特征,在图像中找到感兴趣目标区域,即框定船舶的位置;最后,通过多个全连接层的组合,将高维特征映射到一个4元组中,再运用分类函数输出每一类船舶的概率值,概率值最大的则为该船舶的类别。同时为解决云雾遮挡和海岸背景的干扰,采用了一种负样本增强学习的方法,在样本数据集中加入了大量只含有云雾和海岸背景的图片,进行负样本扩充,增强网络模型对云雾及海岸背景的特征学习能力,以此解决复杂海情的影响。实验结果表明,所提方法有效解决了复杂海情条件下的船舶识别难,以及小目标船舶识别难的问题,实现了复杂海情条件下的船舶识别。同时,与现有成熟的深度学习目标识别算法相比,本文算法的精确度和召回率分别提升了6.98%和18.17%,所训练的模型具有良好的泛化能力和鲁棒性。  相似文献   

Torsional dynamic response of a large‐diameter pipe pile in viscoelastic saturated soil     

Changjie Zheng  Hanlong Liu  Xuanming Ding  Yaru Lv 《国际地质力学数值与分析法杂志》2014,38(16):1724-1743

An analytical solution is developed in this paper to investigate the dynamic response of a large‐diameter end‐bearing pipe pile subjected to torsional loading in viscoelastic saturated soil. The wave propagation in saturated soil and pile are simulated by Biot's two‐phased linear theory and one‐dimensional elastic theory, respectively. The dynamic equilibrium equations of the outer soil, inner soil, and pile are established. The solutions for the outer and inner soils in frequency domain are obtained by Laplace transform technique and the separation of variables method. Then, the dynamic response of the pile is obtained on the basis of the perfect contacts between the pile and the outer soil as well as the inner soil. The results in this paper are compared with that of a solid pile in elastic saturated soil to verify the validity of the solution. Furthermore, the solution in this paper is compared with the classic plane strain solution to verify the solution further and check the accuracy of the plane strain solution. Numerical results are presented to analyze the vibration characteristics and illustrate the effect of the soil parameters and the geometry size of the pile on the complex impedance and velocity admittance of the pile head. Finally, the displacement of the soil at different depth and frequency is analyzed. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

基于分段副产物瞬时选择性的反应器网络综合     

胡仰栋  周勇  伍联营 《中国海洋大学学报(自然科学版)》2020,50(3):61-66

针对第三类反应体系的反应器网络综合问题,提出将串联反应以反应物到目的产物的反应步数为依据的新分段策略。通过比较不分段目的产物、不分段目的产物和中间产品、分段副产物和分段目的产物这四种不同的瞬时选择性,提出以分段副产物瞬时选择性为参数,以其对关键组分浓度或转化率的导数为依据选择各阶段最合适的反应器,以目的产物总选择性最大为目标采用遗传算法优化反应器网络。通过三个实例验证了本文所建立方法在解决复杂反应反应器网络综合问题的有效性,且本方法同样适用于简单反应体系。  相似文献